Paper 14.2

PREDICTION OF SURFACE TENSION OF ALLOYS BASED ON THERMODYNAMIC AND THERMOPHYSICAL DATA

 

Picha Radim1, Vřešťál Jan1, Kroupa Aleš 2

 

1Institute of Theoretical and Physical Chemistry, Faculty of Science, Masaryk University, Kotlářská 2, 611 37 Brno, Czech Republic

2Institute of Physics of Materials, Academy of Science of Czech Republic, Žižkova 22, 616 62  Brno, Czech Republic

 

Thermodynamic database, created in the Masaryk university Brno and in the Institute of Physics of Materials AS CR Brno for calculation of phase diagrams of low melting metals on the base of literature data [1] was used for calculation of surface tension of alloys of these metals. Excess Gibbs energy of liquid phase from the database was taken for calculations by using of our own code exploiting Butler equation [2] for binary systems.

 

Surface tension of pure metals, necessary for these calculations, were taken from experimental and published measurements performed in the Institute of Metallurgy and Material Science PAS Krakow [3-7]. Comparison of calculated results of surface tension of alloys with experimental ones [3-7] will be presented.

 

Literature:

1.      Kroupa, A., Vizdal, J., Zemanova, A., Vřešťál, J.: Proceedings on CD: Working Group 1 and 2 Meeting COST Materials Action 531, Institute of Physics of Materials ASCR Brno and Masaryk University Brno, June 2003.

2.      Butler, J.A.V.: Proc.Roy.Soc., A135, 348 (1932)

3.      Gasior, W., Moser, Z., Pstrus, J.: J. Phase Equilib. 24 (6): 504 (2003)

4.      Gasior, W., Pstrus, J., Moser, Z., et al.: J. Phase Equilib. 24 (1): 40 (2003)

5.      Moser, Z., Gasior, W., Pstrus, J.: J. Electron. Mater. 30 (9): 1104 (2001)

6.      Moser, Z., Gasior, W., Pstrus, J., et al.: J. Electron. Mater. 30 (9): 1120 (2001)

7.      Gasior, W., Moser, Z., Pstrus, J.: J. Phase Equilib. 22 (1): 20 (2001)

 

This work is supported by the COST projects Nos. OC 531.001 and OC 531.002 of Ministry of Education of Czech Republic.